近日，材料化学领域的顶尖期刊、英国皇家化学学会旗下Journal of Materials Chemistry C以封面论文的形式发表了材料冶金化学学部分子材料化学与技术研究所温和瑞教授课题组的最新研究成果。利用2,2’-联咪唑制备了一例单核DyIII配合物，由于硝酸根和配位水分子的存在，其可通过氢键拓展为二维超分子层。研究表明，这例DyIII基单分子磁体的有效能垒超过70 K，并且在35 ℃和相对湿度100%的条件下，其电导率为1.16×10−3 S cm−1。这是第一例具有优异质子传导性能的DyIII基单分子磁体，推动了稀土多功能材料的发展。该成果受到编辑和审稿人的高度评价，以封面论文的形式发表在2021年第2期的《材料化学C》上，同时入选热点论文。封面设计坚持绿色、环保、健康的理念，同时融入代表江西理工大学的冶金女神和校本部大门等元素，彰显了江西理工大学对国家高端稀土功能材料发展的新贡献。论文第一作者为博士生朱水东，第一通讯作者为温和瑞教授，中国科学院福建物质结构研究所和中国科学院化学所为参与单位。本工作得到了国家自然科学基金和江西省自然科学基金的资助。
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近三年，温和瑞教授课题组围绕具有优良光电磁性能的分子功能材料开展持续研究，三篇论文被选为期刊外封面，两篇论文入选ESI高被引论文，大大提升了我校化学学科在全国范围内的影响力。
主要论文包括：
1. S.-D. Zhu, J.-J. Hu, L. Dong, H.-R. Wen,* S.-J. Liu,* Y.-B. Lu and C.-M. Liu*, Multifunctional Zn(II)-Yb(III) Complex Enantiomers Showing Second-Harmonic Generation, Near-Infrared Luminescence, Single-Molecule Magnet and Proton Conduction, J. Mater. Chem. C 2020, 8, 16032-16041. (Hot Paper).
2. S.-D. Zhu, L. Dong, J.-J. Hu, H.-R. Wen,* Y. Lu, W.-H. Deng, C.-M. Liu,* S.-J. Liu, G. Xu and Z.-H. Fu*, A Proton Conducting Single-ion Magnet Based on a Mononuclear Dy(III) Complex, J. Mater. Chem. C 2021, 9, 481-488. (Hot Paper, Cover Paper)
3. H.-R. Wen,* J.-J. Hu, K. Yang, J.-L. Zhang, S.-J. Liu,* J.-S. Liao and C.-M. Liu*, Family of Chiral ZnII−LnIII (Ln = Dy and Tb) Heterometallic Complexes Derived from the Amine−Phenol Ligand Showing Multifunctional Properties, Inorg. Chem. 2020, 59, 2811-2824.
4. S.-L. Yao, S.-J. Liu,* X.-M. Tian, T.-F. Zheng, C. Cao, C.-Y. Niu, Y.-Q. Chen, J.-L. Chen, H. Huang and H.-R. Wen*, A ZnII-Based Metal−Organic Framework with a Rare tcj Topology as a Turn-On Fluorescent Sensor for Acetylacetone, Inorg. Chem. 2019, 58, 3578–3581. (ESI热点论文和高被引论文)
5. X.-N. Zhang, J.-J. Hu, J.-L. Zhang, S.-J. Liu,* J. Liao and H.-R. Wen*, Multifunctional ZnII-LnIII (Ln = Tb, Dy) Complexes Based on the Amine-Phenol Ligand with Field-Induced Slow Magnetic Relaxation, Luminescence, and Proton Conduction, New J. Chem. 2021, 45, 3351–3736. (Cover Paper)
6. T.-F. Zheng, X.-M. Tian, L.-H. Wu, S.-J. Liu,* S.-L. Yao, K.-H. He,* H. Huang, J. Liao, J.-L. Chen and H.-R. Wen*, Two GdIII Complexes with Different Structures and Magnetocaloric Properties Induced by Metal Ion Sources, New J. Chem. 2019, 43, 18445-18450.
7. H.-R. Wen,* J.-L. Zhang, F.-Y. Liang, K. Yang, S.-J. Liu,* J.-S. Liao and C.-M. Liu, TbIII/3d–TbIII Clusters Derived from 1,4,7–Triazacyclononane-Based Hexadentate Ligand with Field-Induced Slow Magnetic Relaxation and Oxygen-Sensitive Luminescence, New J. Chem. 2019, 43, 4067-4074.
8. S.-L. Yao, X.-M. Tian, L.-Q. Li, S.-J. Liu,* T.-F. Zheng, Y.-Q. Chen, D.-S. Zhang, J.-L. Chen, H.-R. Wen* and T.-L. Hu*, A CdII-Based Metal-Organic Framework with pcu Topology as Turn-On Fluorescent Sensor for Al3+, Chem. Asian J. 2019, 14, 3648-3654.
9. X.-M. Tian, S.-L. Yao, C.-Q. Qiu, T.-F. Zheng, Y.-Q. Chen, H. Huang, J.-L. Chen, S.-J. Liu* and H.-R. Wen, Turn-On Luminescent Sensor toward Fe3+, Cr3+, and Al3+ Based on a Co(II) Metal-Organic Framework with Open Functional Sites, Inorg. Chem. 2020, 59(5), 2803-2810. (ESI高被引论文)
10. S.-L. Yao, T.-F. Zheng, X.-M. Tian, S.-J. Liu,* C. Cao, Z.-H. Zhu, Y.-Q. Chen,* J.-L. Chen and H.-R. Wen*, Dicarboxylate-Induced Structural Diversity of Luminescent ZnII/CdII Coordination Polymers Derived from V-Shaped Bis-benzimidazole, CrystEngComm 2018, 20, 5822-5832.
11. Z. Zou, G. Peng, J. Hu, J. Liao, H.-R. Wen,* F. Liu and J. Zhong*, Microstructure and Luminescence Properties of a Ce3+-Doped Lu3Al5O12/Al2O3 Eutectic Grown by the Micropulling Down Method, J. Alloys Comp. 2019, 794, 144-152.
12. B. Liu, X. Wang, H. Liu,* Y. Zhai, L. Li* and H.-R. Wen*, 2D MOF with Electrochemical Exfoliated Graphene for Nonenzymatic Glucose Sensing: Central Metal Sites and Oxidation Potentials, Anal. Chim. Acta 2020, 1122, 9-19.
13. Wen-Hai Yi, Jun-Jie Hu, Jia-Li Zhang, He-Rui Wen,* Sui-Jun Liu* and Yun-Wu Li*, Dy(III) and Zn/Ni-Dy(III) Complexes Derived from Polyamine Phenol Ligand with Slow Magnetic Relaxation and Luminescent Properties, Chinese J. Inorg. Chem. 2020, 36(4), 607-619. (Cover Paper)
14. S.-L. Yao, Y.-C. Xiong, X.-M. Tian, S.-J. Liu,* H. Xu, T.-F. Zheng,* J.-L. Chen and H.-R. Wen*, A Multifunctional Benzothiadiazole-Based Fluorescence Sensor toward Al3+, Cr3+ and Fe3+, CrystEngComm 2021, 23(9), 1898-1905.
（文/刘遂军 审核/王瑞祥）
